CRYSTALLOGRAPHIC EVIDENCE FOR INTERMOLECULAR HYDROGEN-BONDING BETWEEN ARYL GROUPS AND OH GROUPS IN SILANOLS

被引：7

作者：

ALJUAID, SS ^{[1
]}

ALNASR, AKA ^{[1
]}

EABORN, C ^{[1
]}

HITCHCOCK, PB ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 429卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)83258-J

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In crystals of the silanols (Me3Si)3CSiPh(X)OH (X = I or OMe) there is intermolecular-pi ... HO bonding between a phenyl group in one molecule and an OH group in another, and there are probably intramolecular-pi ... HO interactions in two silanols previously reported to show no hydrogen bonding. It is suggested that similar interactions should exist for OH groups attached to other metals or metalloids.

引用

页码：C9 / C13

页数：5

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