ROOM-TEMPERATURE POLYMERIZATION AND SPECTROSCOPIC ANALYSIS OF GERMANIUM PHTHALOCYANINE POLYMERS

被引：6

作者：

HOHOL, MD ^{[1
]}

URBAN, MW ^{[1
]}

机构：

[1] N DAKOTA STATE UNIV,DEPT POLYMERS & COATINGS,FARGO,ND 58105

来源：

POLYMER | 1993年 / 34卷 / 09期

关键词：

SYNTHESIS; SPECTROSCOPIC ANALYSIS; GERMANIUM PHTHALOCYANINE POLYMERS;

D O I：

10.1016/0032-3861(93)90454-I

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This paper describes a one-step, room temperature synthesis utilizing ultrasonic energy of a coaxially stacked poly(phthalocyanato) germanium oxide ([Ge(Pc)O]n) from Ge(Pc)Cl2. The synthesis is conducted in the presence of a sodium chalcogenide. Based on photoacoustic FTi.r. and u.v.-vis. spectroscopic analysis, the mechanism of the [Ge(Pc)O]n formation is proposed. The use of isotopic H2O/D2O exchange is also utilized in an effort to reveal the role of traces of water present during the polymerization reaction.

引用

页码：1995 / 2002

页数：8

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