DIMERIC ANTIMONY COMPLEXES CAPTURING DIMETHYLAMINE AS A NEUTRAL DONOR - SYNTHESES AND STRUCTURAL CHARACTERIZATION OF [SBCL2(NHME2)(MU-OET)]2 AND [SBCL(NHME2)(MU-NBU-T)]2

被引：31

作者：

EDWARDS, AJ ^{[1
]}

LEADBEATER, NE ^{[1
]}

PAVER, MA ^{[1
]}

RAITHBY, PR ^{[1
]}

RUSSELL, CA ^{[1
]}

WRIGHT, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1994年 / 09期

关键词：

D O I：

10.1039/dt9940001479

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The two dimeric antimony complexes, [SbCl2(NHMe2)(mu-OEt)]2 and [SbCl(NHMe2)(mu-NBu(t))]2 have been synthesised by the reaction of SbClx(NMe2)3-x with EtOH (x = 2) or NH2But (x = 1) respectively; both complexes exhibit the co-ordination of a dimethylamine ligand to antimony and intricate intermolecular association in the solid state.

引用

页码：1479 / 1482

页数：4

共 30 条

[1] PREPARATIONS AND REACTIONS OF TRIS(DIALKYLAMINO)BISMUTHINE [J].

ANDO, F ;

HAYASHI, T ;

OHASHI, K ;

KOKETSU, J .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1975, 37 (09) :2011-2013

[2] THE BIS(CYCLOPENTADIENYL)THALLATE(I) ANION ISOELECTRONIC WITH STANNOCENE [J].

ARMSTRONG, DR ;

HERBSTIRMER, R ;

KUHN, A ;

MONCRIEFF, D ;

PAVER, MA ;

RUSSELL, CA ;

STALKE, D ;

STEINER, A ;

WRIGHT, DS .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1993, 32 (12) :1774-1776

[3]

ARMSTRONG DR, 1993, ANGEW CHEM, V105, P1087

[4]

ARMSTRONG DR, IN PRESS J AM CHEM S

[5] THE STRUCTURE OF TETRAMETHYLDISTIBINE [J].

ASHE, AJ ;

LUDWIG, EG ;

OLEKSYSZYN, J ;

HUFFMAN, JC .

ORGANOMETALLICS, 1984, 3 (02) :337-338

[6] STRUCTURE AND MASS-SPECTRA OF THE SERIES SB(OET)3-SBCL3 [J].

BINDER, GE ;

SCHWARZ, W ;

ROZDZINSKI, W ;

SCHMIDT, A .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1980, 471 (12) :121-130

[7] THE SYNTHESIS AND CHARACTERIZATION BY INFRARED AND RAMAN-SPECTROSCOPY OF SOME AMMINE, METHYLAMINE, DI-METHYLAMINE AND TRI-METHYLAMINE AND ANILINE COMPLEXES OF GROUP-VB (AS, SB AND BI) TRIHALIDES [J].

BISWAS, AK ;

HALL, JR ;

SCHWEINSBERG, DP .

INORGANICA CHIMICA ACTA-ARTICLES, 1983, 75 (01) :57-64

[8] SYNTHESIS AND STRUCTURE OF SESB2CL2(NCME3)4 - A COMPOUND WITH A SELENIUM ATOM COORDINATED BY 3 NITROGEN-ATOMS [J].

BJORGVINSSON, M ;

ROESKY, HW ;

PAUER, F ;

SHELDRICK, GM .

CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (04) :767-769

[9] X-RAY CRYSTAL-STRUCTURE OF [BI(NME2)3] [J].

CLEGG, W ;

COMPTON, NA ;

ERRINGTON, RJ ;

FISHER, GA ;

GREEN, ME ;

HOCKLESS, DCR ;

NORMAN, NC .

INORGANIC CHEMISTRY, 1991, 30 (24) :4680-4682

[10]

COTTON FA, 1988, ADV INORG CHEM RAD, P283

← 1 2 3 →