STRUCTURE OF AN ORGANOMETALLIC INTERCALATE - SINGLE-CRYSTAL X-RAY AND POWDER NEUTRON-DIFFRACTION STUDY OF [SNS2(CO(ETA-C5H5)2)0.31] AND [SNS2(CO(ETA-C5D5)2)0.31]

被引：24

作者：

OHARE, D ^{[1
]}

EVANS, JSO ^{[1
]}

WISEMAN, PJ ^{[1
]}

PROUT, K ^{[1
]}

机构：

[1] CHEM CRYSTALLOG LAB,OXFORD OX1 3PD,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 09期

关键词：

D O I：

10.1002/anie.199111561

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Layer compounds can change from semiconductors to superconductors by intercalation of metallocenes such as [Co(eta-5-C5H5)2]. However, the molecular structure of these interesting materials was hitherto unclear. Are the Cp planes of the organometal compound arranged perpendicular or parallel to the layers of the host lattice (see picture on the right)? In the title compound parallel, at least according to comprehensive structure investigations. [GRAPHICS]

引用

页码：1156 / 1158

页数：3

共 8 条

[1] GROWTH BY IODINE VAPOR TRANSPORT AND CRYSTAL-STRUCTURES OF LAYER COMPOUNDS IN SERIES SNSXSE2X(0 =] X =] 2),SNXZR1-XSE2(0 =] X =] 1), AND TASXSE2-X(0 =] X =] 2) [J].