A NEW CONCEPT IDEAL ORGANIZED SOLUTION - COMPARISON OF RANDOM MIXING SOLUTIONS AND IDEAL ORGANIZED SOLUTION

被引:13
作者
SHINODA, K
机构
[1] Department of Physical Chemistry, Division of Materials Science and Engineering, Yokohama National University, Tokiwadai
关键词
D O I
10.1021/la00060a002
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In order to clarify "organized solutions", a comparison among an ideal solution, regular solutions, and organized solutions was carried out, and the differences among these solutions were examined. From the fundamental differences of the characteristic properties of randomly mixed solutions and organized solutions (systems), a new concept "ideal organized solution" evolved. The ideal solution has earlier been considered to represent ideal cases of all types of solutions, but it is the ideal case of randomly mixed solutions. A new concept "ideal organized solution", which has not been conceived over the long history of physical science, is indispensable as an idealized model of organized solutions, i.e., self-organized systems. An ideal mixing solution and ideal organized solution are in direct opposition in fundamental respects. The necessity of two ideal solutions, i.e., ideal mixing solution and ideal organized solution, was elucidated. The new concept of two ideal solutions in chemistry may be as revolutionary as the concept of duality of light in physics.
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页码:2877 / 2880
页数:4
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