INTRAMOLECULAR TRANSFER OF CO FROM (ETA(6)-ARENE)CR(CO)(3) COMPLEXES IN STILLE-TYPE PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS

被引：25

作者：

CALDIROLA, P ^{[1
]}

CHOWDHURY, R ^{[1
]}

JOHANSSON, AM ^{[1
]}

HACKSELL, U ^{[1
]}

机构：

[1] UNIV UPPSALA,CTR BIOMED,S-75123 UPPSALA,SWEDEN

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 08期

关键词：

D O I：

10.1021/om00008a041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Arylketones were formed from the Cr(CO)(3) complex of (trialkylstannyl)benzene or chlorobenzene by a palladium-catalyzed cross-coupling reaction in the absence of external CO. The Cr(CO)(3) moiety provides the required CO predominantly by an intramolecular mechanism. Products due to a direct coupling reaction were also observed. The influence of solvent, temperature, substrate, and catalyst on the relative amount of products due to both carbonylative coupling and direct coupling were studied.

引用

页码：3897 / 3900

页数：4

共 48 条

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