MILLIMETER-WAVE SPECTRUM OF NCS RADICAL IN THE GROUND 2-PI STATE

The rotational transitions of NCS have been observed in the 1 to 3 mm wavelength region in a hollow cathode discharge in a gas mixture of CS2 (approximately 1 mTorr) and N2 (approximately 30 mTorr). The molecular constants in the ground state are determined by fitting the observed frequencies to the standard Hamiltonian for 2PI states. The accuracy of the molecular constants are greatly improved compared with the values obtained from the optical data. The lines in the excited vibronic states have also been observed. The analysis including those excited state lines is in progress and the results will be published separately.