NOVEL BONDING OF TERTIARY DIPHOSPHINES TO METAL RING CARBONYL-COMPLEXES

被引：9

作者：

BROWN, DA ^{[1
]}

BURNS, J ^{[1
]}

ELGAMATI, I ^{[1
]}

GLASS, WK ^{[1
]}

KREDDAN, K ^{[1
]}

SALAMA, M ^{[1
]}

CUNNINGHAM, D ^{[1
]}

HIGGINS, T ^{[1
]}

MCARDLE, P ^{[1
]}

机构：

[1] NATL UNIV IRELAND UNIV COLL GALWAY,DEPT CHEM,GALWAY,IRELAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 09期

关键词：

D O I：

10.1039/c39920000701

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tertiary diphosphines form complexes with various metal ring carbonyl cations of new and novel structural types including ring adducts, e.g. [(eta-4-C7H9-5-exo-eta-1-PPh2CH2PPh2)Fe(CO)3]BF4 diphosphine bridged ring dimers, e.g. Ph2P(CH2)2PPh2[(eta-4-C7H9)Fe(CO)3]2[BF4]2 and diphosphine bridged ring-metal dimers, e.g. [(eta-5-C5H5)Fe(CO)2PPh2(CH2)3PPh2(exo-eta-6-C7H7)Cr(CO)3][BF4]2.

引用

页码：701 / 702

页数：2

共 5 条

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[2] NUCLEOPHILIC-SUBSTITUTION AND ADDITION-REACTIONS OF THE TRICARBONYL(ETA-1,5-CYCLOHEPTADIENYLIUM)IRON CATION [J].

BROWN, DA ;

CHAWLA, SK ;

GLASS, WK ;

HUSSEIN, FM .

INORGANIC CHEMISTRY, 1982, 21 (07) :2726-2732

[3]

HACKETT P, 1975, INORG CHIM ACTA, V12, P19

[4] CHEMISTRY OF BIS(DIPHENYLPHOSPHINO)METHANE [J].

PUDDEPHATT, RJ .

CHEMICAL SOCIETY REVIEWS, 1983, 12 (02) :99-127

[5]

REYER DL, 1977, J ORGANOMET CHEM, V131, P153

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