SODIUM-ETHANOL - SUPERIOR REAGENT FOR THE REDUCTIVE DEHALOGENATION OF POLYCHLORINATED ALICYCLIC MOLECULES

被引:46
作者
LAP, BV [1 ]
PADDONROW, MN [1 ]
机构
[1] NEW S WALES INST TECHNOL,DEPT CHEM,BROADWAY 2007,NEW S WALES,AUSTRALIA
关键词
D O I
10.1021/jo00394a054
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Diels-Alder reactions of hexachlorocyclopentadiene (1a) and 1, 2, 3, 4-tetrachloro-5, 5-dimethoxycyclopentadiene (1b) with a wide range of dienophiles generally give excellent yields of adducts with a high degree of stereospecificity. For these reasons la and lb are often used as synthons for cyclopentadiene and cyclopentadienone, respectively. © 1979, American Chemical Society. All rights reserved.
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页码:4979 / 4981
页数:3
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