DIRECT FORMATION OF FORMIC-ACID FROM CARBON-DIOXIDE AND DIHYDROGEN USING THE [(RH(COD)CL)2]-PH2P(CH2)4PPH2 CATALYST SYSTEM

被引:155
作者
GRAF, E [1 ]
LEITNER, W [1 ]
机构
[1] UNIV REGENSBURG,INST ANORGAN CHEM,UNIV STR 31,W-8400 REGENSBURG,GERMANY
关键词
D O I
10.1039/c39920000623
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Formic acid, isolable as sodium formate from the reaction mixture, is produced directly from hydrogen and carbon dioxide with yields up to 1150 moles per mole of rhodium using a homogeneous catalyst formed in situ from [{Rh(cod)Cl}2] and Ph2P(CH2)4PPh2; the precious metal is recovered during work-up in a catalytically active form.
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页码:623 / 624
页数:2
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