DIRECT FORMATION OF FORMIC-ACID FROM CARBON-DIOXIDE AND DIHYDROGEN USING THE [(RH(COD)CL)2]-PH2P(CH2)4PPH2 CATALYST SYSTEM

被引：155

作者：

GRAF, E ^{[1
]}

LEITNER, W ^{[1
]}

机构：

[1] UNIV REGENSBURG,INST ANORGAN CHEM,UNIV STR 31,W-8400 REGENSBURG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 08期

关键词：

D O I：

10.1039/c39920000623

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Formic acid, isolable as sodium formate from the reaction mixture, is produced directly from hydrogen and carbon dioxide with yields up to 1150 moles per mole of rhodium using a homogeneous catalyst formed in situ from [{Rh(cod)Cl}2] and Ph2P(CH2)4PPh2; the precious metal is recovered during work-up in a catalytically active form.

引用

页码：623 / 624

页数：2

共 13 条

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