ION-PAIR BINDING BY A UREA IN CHLOROFORM SOLUTION

被引:169
作者
SMITH, PJ [1 ]
REDDINGTON, MV [1 ]
WILCOX, CS [1 ]
机构
[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260
关键词
D O I
10.1016/S0040-4039(00)60012-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An arylurea has been found to bind very strongly to ion pairs containing sulfonates, phosphates, and carboxylates in chloroform. The data suggest that complexation is due to hydrogen bonding between the urea and the anion. Applications to the design of molecular catalysts are envisioned.
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页码:6085 / 6088
页数:4
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