REACTIONS OF HALOBENZENES WITH CYANOMETHYL ANION IN LIQUID-AMMONIA BY THE SRN1 MECHANISM

被引:17
作者
ROSSI, RA
ROSSI, RHD
PIERINI, AB
机构
[1] Departamento de Quimica Orgdnica, Facultad de Ciencias Quimicas, Universidad National de Cordoba, Est., Cdrdoba
关键词
D O I
10.1021/jo01329a015
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reactions of fluoro-, chloro-, bromo-, and iodobenzenes with cyanomethyl anion in liquid ammonia havebeen studied with regard to the product distribution (1, 2-diphenylethane/phenylacetonitrile ratio). All the substratesgave about the same ratio. The addition of good electron acceptors such as naphthalene, anthracene, or pyridineinhibited the photostimulated reactions and gave a slight increase in the yield of 1, 2-diphenylethane. In reactionsstimulated by electrons the presence of naphthalene or benzoate ion as electron acceptors makes the yield of phenylacetonitrile drop almost to zero, whereas yields of the other products increase. Alternative reaction pathwaysare suggested. © 1979, American Chemical Society. All rights reserved.
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页码:2662 / 2667
页数:6
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