2-DIMENSIONAL NATURE OF BEDT-TSEF COMPOUNDS

被引：27

作者：

KOBAYASHI, A

KATO, R

NAITO, T

KOBAYASHI, H

机构：

[1] UNIV TOKYO,INST SOLID STATE PHYS,MINATO KU,TOKYO 106,JAPAN

[2] TOHO UNIV,FAC SCI,DEPT CHEM,FUNABASHI,CHIBA 274,JAPAN

来源：

SYNTHETIC METALS | 1993年 / 56卷 / 01期

关键词：

MOLECULAR CONDUCTOR; TETRASELENAFULVALENE; DISELENADITHIAFULVALENE;

D O I：

10.1016/0379-6779(93)90376-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have obtained a variety of highly conducting cation radical salts of BEDT-TSeF(BETS)(bis-(ethylenedithio)tetraselenafulvalene) and asymmetrical pi-donors having a half of BETS skeleton, BEDT-STF(bis-(ethylenedithio)diselenadithiafulvalene), EDST((ethylenedithio)diselenadithiafulvalene) and EOST(4,5-ethylenedithio-4', 5'-(2-oxatrimethylenedithio)diselenadithiafulvalene). Crystal structure analysis of cation radical salts of BETS has revealed that BETS molecule has strong tendency to form 2-dimensional molecular arrangement. The crystal structures and electrical conductivities of radical salts of BEDT-STF, EDST and EOST were examined.

引用

页码：2078 / 2083

页数：6

共 6 条

[1] KAJITA K, SOLID STATE COMMUN, V70, P1181
[2] STRUCTURAL AND PHYSICAL-PROPERTIES OF KAPPA AND THETA-(BEDT-TSEF)2TAF6 - MOLECULAR DESIGN AIMED TOWARD THE 2-DIMENSIONAL METAL
KATO, R
KOBAYASHI, A
MIYAMOTO, A
KOBAYASHI, H
[J]. CHEMISTRY LETTERS, 1991, (06) : 1045 - 1048
[3] KATO R, 1991, SYNTHETIC MET, V41, P2093
[4] KOBAYASHI H, IN PRESS
[5] STRUCTURE AND ELECTRICAL-PROPERTIES OF THETA-TYPE AND KAPPA-TYPE BEDT-TSEF SALTS WITH BROMOMERCURATE ANIONS
NAITO, T
MIYAMOTO, A
KOBAYASHI, H
KATO, R
KOBAYASHI, A
[J]. CHEMISTRY LETTERS, 1991, (11) : 1945 - 1948
[6] SYNTHESIS OF 4,5-ETHYLENEDITHIO-4',5'-(2-OXATRIMETHYLENEDITHIO)-TETRATHIAFULVALENE (EOTT) AND ELECTRICAL CONDUCTIVITIES OF THEIR ION-RADICAL SALTS
NAKANO, H
YAMADA, K
NOGAMI, T
SHIROTA, Y
MIYAMOTO, A
KOBAYASHI, H
[J]. CHEMISTRY LETTERS, 1990, (11) : 2129 - 2132

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