ELECTROCHEMICAL EPOXIDATION OF OLEFINS

被引：9

作者：

van der Eijk, J. M. ^{[1
]}

Peters, Th. J. ^{[1
]}

de Wit, N. ^{[1
]}

Colijn, H. A. ^{[1
]}

机构：

[1] Amsterdam Shell Res BV, Koninklijke Shell Lab, NL-1003 AA Amsterdam, Netherlands

来源：

CATALYSIS TODAY | 1988年 / 3卷 / 2-3期

关键词：

D O I：

10.1016/0920-5861(88)87014-7

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Propene and the four isomeric butenes are selectively oxidized to the respective epoxides by reaction with electrachemically generated silver(II)-pyridine ions. From kinetic studies, the epoxidation was derived to involve the transfer of an electrophilic oxygen atom from a transient silver(III)-oxide complex to the homogeneously dissolved olefin.

引用

页码：259 / 266

页数：8