SELF-AGGREGATION OF ALPHA,OMEGA-ALKANEDIOLS INTO 3-D CRYSTALLITES AS STUDIED AT INTERFACES - THE SYSTEM OF ALPHA-OMEGA-DOCOSANEDIOL

被引：45

作者：

POPOVITZBIRO, R ^{[1
]}

MAJEWSKI, J ^{[1
]}

MARGULIS, L ^{[1
]}

COHEN, S ^{[1
]}

LEISEROWITZ, L ^{[1
]}

LAHAV, M ^{[1
]}

机构：

[1] WEIZMANN INST SCI, CHEM SERV UNIT, IL-76100 REHOVOT, ISRAEL

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 19期

关键词：

D O I：

10.1021/j100070a005

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Spreading of the bolaamphiphile alpha,omega-docosanediol, HO(CH2)(22)OH, on water results in spontaneous aggregation into embryonic 3-D crystallites. These crystallites have been analyzed by cryo-transmission electron microscopy, scanning force microscopy, X-ray reflectivity, and external reflection Fourier transform infrared spectroscopy. The molecules are aligned in an almost perpendicular fashion in a rectangular cell, and the crystallites are about five molecular layers thick.

引用

页码：4970 / 4972

页数：3

共 17 条

[1] The structure of thin films. Part IX. Dibasic substances. [J].

Adam, NK ;

Jessop, G .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-CONTAINING PAPERS OF A MATHEMATICAL AND PHYSICAL CHARACTER, 1926, 112 (761) :376-380

[2] FORMATION OF A CRYSTALLINE MONOLAYER OF FOLDED MOLECULES BY SOLUTION SELF-ASSEMBLY OF ALPHA,OMEGA-ALKANEDIOIC ACIDS ON SILVER [J].

ALLARA, DL ;

ATRE, SV ;

ELLIGER, CA ;

SNYDER, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (05) :1852-1854

[3]

ALSNIELSEN J, 1989, NATO ADV SCI I B-PHY, V211, P113

[4]

BOHM C, 1994, LANGMUIR, V10, P830

[5]

DLUHY RA, 1990, FOURIER TRANSFORM IN, V447, P192

[6] COUPLED EXTERNAL REFLECTANCE FT-IR MINIATURIZED SURFACE-FILM APPARATUS FOR BIOPHYSICAL STUDIES [J].

FLACH, CR ;

BRAUNER, JW ;

MENDELSOHN, R .

APPLIED SPECTROSCOPY, 1993, 47 (07) :982-985

[7] STUDIES ON SPREADING COLLAPSE AND TEMPERATURE AND COMPRESSION RATE EFFECTS ON MONOLAYERS OF ALPHA,OMEGA-DICARBOXYLIC ACIDS [J].

JEFFERS, PM ;

DAEN, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (07) :2368-&

[8] CRYSTAL-STRUCTURE OF 2,7-DIMETHYL-2,7-OCTANEDIOL TETRAHYDRATE [J].

JEFFREY, GA ;

MASTROPAOLO, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (FEB) :552-556

[9] ELECTRON-DIFFRACTION AND IMAGING OF UNCOMPRESSED MONOLAYERS OF AMPHIPHILIC MOLECULES ON VITREOUS AND HEXAGONAL ICE [J].

MAJEWSKI, J ;

MARGULIS, L ;

JACQUEMAIN, D ;

LEVEILLER, F ;

BOHM, C ;

ARAD, T ;

TALMON, Y ;

LAHAV, M ;

LEISEROWITZ, L .

SCIENCE, 1993, 261 (5123) :899-902

[10]

MAJEWSKI J, UNPUB

← 1 2 →