A NOVEL HIGHLY STEREOSELECTIVE SYNTHESIS OF PYRROLIDINES AND THEIR DERIVATIVES THROUGH THERMAL CYCLIZATION REACTION OF N-[BIS(TRIMETHYLSILYL)METHYL]-1-AZA-1,3-DIENES

被引：13

作者：

PALOMO, C

AIZPURUA, JM

GARCIA, JM

LEGIDO, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 07期

关键词：

D O I：

10.1039/c39910000524

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of the thermal intramolecular cyclization of N-[bis(trimethylsilyl)methyl]-1-aza-1,3-dienes to give 5-trimethylsilyl-DELTA-2-pyrrolines is reported; two straightforward and highly stereoselective routes to 3,4-disubstituted-5-trimethylsilyl-DELTA-1-pyrrolines and 3,4-disubstituted-2-trimethylsilylpyrrolidines are also described.

引用

页码：524 / 526

页数：3

共 14 条

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