SPIN COUPLING-CONSTANTS AND HYPERFINE TRANSITION FREQUENCIES FOR THE HYDROGEN MOLECULAR ION

被引：24

作者：

BABB, JF

DALGARNO, A

机构：

[1] Institute for Theoretical Atomic and Molecular Physics, Harvard-Smithsonian Center for Astrophysics, Cambridge, MA 02143

来源：

PHYSICAL REVIEW A | 1992年 / 46卷 / 09期

关键词：

D O I：

10.1103/PhysRevA.46.R5317

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

We have calculated for the ten lowest vibrational levels of H-2+ the first-order hyperfine and spin-rotation constants with the inclusion in perturbation theory of the first-order coupling of the electron and nuclear motion and have determined the hyperfine transition frequencies. The calculated frequencies agree to better than 175 kHz with all the experimentally determined hyperfine frequencies for the N = 1 rotational level and to better than 3 kHz for the N = 2 rotational level. Relativistic and radiative effects may account for the remaining discrepancy.

引用

页码：R5317 / R5319

页数：3

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