REACTIONS OF PHENOXIDE ION IN THE GAS-PHASE

被引：11

作者：

BINKLEY, RW ^{[1
]}

TEVESZ, MJS ^{[1
]}

WINNIK, W ^{[1
]}

机构：

[1] CLEVELAND STATE UNIV,DEPT GEOL SCI,CLEVELAND,OH 44115

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 20期

关键词：

D O I：

10.1021/jo00046a037

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

Upon collisionally activated dissociation (CAD) phenoxide ion experiences fragmentation reactions in the gas phase that produce the daughter ions [C6H3]-, [C5H5]-, [C2HO]-, and [C3H3]-. Based upon study of the anions derived from 2,3,4,5,6-pentadeuteriophenol (2), 4-deuteriophenol (3), 3,5-dideuteriophenol (4), and 2,4,6-trideuteriophenol (5), mechanisms for formation of the [C6H3]-, [C5H5]-, and [C2HO]- ions have been proposed.

引用

页码：5507 / 5509

页数：3

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