AMINE COMPLEXES OF BERYLLIUM HYDRIDE

被引：10

作者：

SHEPHERD, LH

TERHAAR, GL

MARLETT, EM

机构：

[1] Research and Development Department, Ethyl Corporation, Baton Rouge

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 04期

关键词：

D O I：

10.1021/ic50074a051

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several tertiary amine complexes of beryllium hydride have been synthesized by three different preparative routes. In the first, trimethylamine is allowed to react with the liquid adduct diethylberyllium-diethylaluminum hydride to produce the crystalline beryllium hydride-trimethylamine complex. The other two procedures involve direct reaction between the amine and polymeric beryllium hydride either by (1) heating the mixture in a sealed system or (2) ball-milling the reactants together. The complexes were characterized by chemical analysis, infrared and nmr spectra, and X-ray powder diffraction measurements. These data, along with molecular weight determinations, indicate that the fundamental unit in every case is the hydrogen-bridged BeH2 dimer. © 1969, American Chemical Society. All rights reserved.

引用

页码：976 / &

共 12 条

[1] DIMETHYLBERYLLIUM .4. SPECTROSCOPIC PROPERTIES OF SOME METHYLBERYLLIUM COMPOUNDS [J].