Change of static electric polarizability upon transition into excited molecular states

被引:45
作者
Seibold, K. [1 ]
Navangul, H. [1 ]
Labhart, H. [1 ]
机构
[1] Univ Zurich, Inst Chem Phys, CH-8006 Zurich, Switzerland
关键词
D O I
10.1016/0009-2614(69)80228-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The change of the static electric polarizability upon transition to the first excited singlet-state of crocetindimethylester. bixinmethylester, lycopene and p-dimethylamino-p'-nitrostilbene has been determined from measurements of electric field induced spectral changes. The molecules were solved in liquids as well as in rigid organic glasses at low temperature. Preliminary quantum-chemical calculations of the change of polarizability upon excitation are reported for crocetindimethylester.
引用
收藏
页码:275 / 279
页数:5
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