VIBRATION-ROTATION COUPLING IN POLYATOMIC-MOLECULES - ADDITIONS TO THE ECKART CONDITIONS

被引：4

作者：

ESSEN, H

机构：

[1] Institute of Theoretical Physics, University of Stockholm

来源：

CHEMICAL PHYSICS | 1979年 / 44卷 / 03期

关键词：

D O I：

10.1016/0301-0104(79)85221-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Additions to the Eckart conditions make it possible to define an essentially unique set of vibrational coordinates which are not the normal coordinates but which have the simpliest possible vibration-rotation coupling. Explicit expressions in these coordinates for general, planar and linear molecules are presented. These differ considerably within this formalism. The vibrational angular momentum algebra takes an especially simple form in these coordinates. Some attention is also given to linear molecules and their hamiltonians. © 1979.

引用

页码：373 / 388

页数：16

共 18 条

[1]

AMAT G, 1958, CAH PHYS, V12, P273

[2] QUANTUM MECHANICAL HAMILTONIAN IN GROUP OPERATOR FORM AND MOLECULAR HAMILTONIAN [J].