A SIMPLE ONE-STEP SYNTHESIS OF SYMMETRICAL THIACROWN ETHERS AND THE MOLECULAR-STRUCTURE OF AN UNUSUAL SANDWICH-LIKE TETRAMETALLIC SILVER THIOCROWN ETHER COMPLEX

被引：25

作者：

EDEMA, JJH

STOCK, HT

BUTER, J

KELLOGG, RM

SMEETS, WJJ

SPEK, AL

VANBOLHUIS, F

机构：

[1] UNIV UTRECHT,DEPT CRYSTAL & STRUCT CHEM,BIJVOET RES CTR,3584 CH UTRECHT,NETHERLANDS

[2] UNIV GRONINGEN,CTR MOLEC STRUCT,9747 AG GRONINGEN,NETHERLANDS

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 03期

关键词：

D O I：

10.1002/anie.199304361

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Also in the presence of functional groups, the 1 and 2 to give thiocrown ethers 3 is achieved in good yields, if B(OiPr)3 Al(OiPr)3) is present. Furthermore a sandwich-like cationic complex [Ag4-(3b)2]4+ was prepared with 3b. This complex is also stable in solution. [GRAPHICS]

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收藏

页码：436 / 439

页数：4

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