ETA(3)-1,3,5-TRIAZACYCLOHEXANE COMPLEXES OF TRIBENZYLCHROMIUM(III)

被引：30

作者：

KOHN, RD

KOCIOKKOHN, G

HAUFE, M

机构：

[1] Institut für Anorganische und Analytische Chemie, Technische Universität Berlin, D-10623 Berlin, Straße des 17

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 501卷 / 1-2期

关键词：

CHROMIUM; BENZYL; 1,3,5-TRIAZACYCLOHEXANE; UV-VIS ABSORPTION SPECTROSCOPY; NMR SPECTROSCOPY; IR SPECTROSCOPY;

D O I：

10.1016/0022-328X(95)05701-P

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,3,5-Tribenzyl-1,3,5-triazacyclohexane ('Bz(3)TAC') and 1,3,5-tricyclohexyl-1,3,5-triazacyclohex ('Cy(3)TAC') react with CrCl3(THF)(3) to the corresponding complexes (Bz(3)TAC)CrCl3 (1a) and (Cy(3)TAC)CrCl3 (1b). These react with benzyl sodium in toluene to the tribenzylchromium(III) complexes (Bz(3)TAC)Cr(CH(2)Ph)(3) (2a) and (Cy(3)TAC)Cr(CH(2)Ph)(3) (2b). The crystal and molecular structure of 2b . 1.5 toluene has been determined by X-ray diffraction.

引用

页码：303 / 307

页数：5

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