MIGRATION OF TERT-BUTYLDIMETHYLSILYL PROTECTING GROUPS

被引：102

作者：

JONES, SS

REESE, CB

机构：

[1] Department of Chemistry, King's College, London WC2R 2LS, Strand

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 11期

关键词：

D O I：

10.1039/p19790002762

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Isomeric 2′- and 3′-O-t-butyldimethylsilylribonucleoside derivatives (2) and (3) undergo interconversion by a first-order equilibration reaction. This intramolecular reaction takes place particularly readily in methanol solution and in the presence of base.

引用

页码：2762 / 2764

页数：3

共 11 条

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