REVERSE COPE ELIMINATIONS - PYRROLIDINE AND PIPERIDINE N-OXIDES BY INTRAMOLECULAR ADDITION OF N,N-DISUBSTITUTED HYDROXYLAMINES TO UNACTIVATED DOUBLE-BONDS

被引：58

作者：

CIGANEK, E

机构：

[1] Medical Products Department, E. I. duPont de Nemours and Co., Wilmington

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 10期

关键词：

D O I：

10.1021/jo00297a011

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-(4-Pentenyl)- and N-(5-hexenyl)-N-methylhydroxylamine and some of their derivatives cyclize under mild conditions in a concerted reverse Cope elimination to give 2-alkylpyrrolidine and 2-alkylpiperidine N-oxides. © 1990, American Chemical Society. All rights reserved.

引用

页码：3007 / 3009

页数：3

共 24 条

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