ZWITTERIONIC SPECIES FROM DEPROTONATION OF ETA-6-ARENE-ETA-5-CYCLOPENTADIENYLIRON CATIONS AND THEIR REACTIONS AS NUCLEOPHILES

被引：37

作者：

SUTHERLAND, RG

STEELE, BR

DEMCHUK, KJ

LEE, CC

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 181卷 / 02期

基金：

英国医学研究理事会;

关键词：

D O I：

10.1016/S0022-328X(00)82833-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A variety of η6-arene-η5-cyclopentadienyliron cations in which the arene ligand has an α-carbon substituent containing one or more hydrogens can be deprotonated with base to give the corresponding neutral zwitterionic species. These zwitterions can react in situ as nucleaphiles with different substrates such as CH3I, other organic halides. CO2 and CS2 to give a wide range of synthetic applications. © 1979.

引用

收藏

页码：411 / 424

页数：14

相关论文

共 16 条

[1]

ABBAYES HD, 1977, J ORG CHEM, V42, P4104

[2] SYNTHESIS AND DEPROTONATION OF ETA-6-ARENE-ETA-5-CYCLOPENTADIENYLIRON(II) COMPLEXES BEARING NH2, OH-OR-SH SUBSTITUENTS [J].

HELLING, JF ;

HENDRICKSON, WA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 168 (01) :87-95

[3] PI-CYCLOHEXADIENYLIRON COMPLEXES BEARING EXOCYCLIC DOUBLE-BONDS [J].

HELLING, JF ;

HENDRICKSON, WA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 141 (01) :99-105

[4] USE OF CARBONYLCHROMIUM GROUPS FOR SELECTIVE ACTIVATION OF ARENE SUBSTITUENTS [J].

JAOUEN, G ;

MEYER, A ;

SIMONNEAUX, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (20) :813-814

[5] SYNTHESIS AND UNEXPECTED STRUCTURE OF ETA5-CYCLOPENTADIENYL-ETA6-FLUORENYLIRON [J].

JOHNSON, JW ;

TREICHEL, PM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (05) :1427-1436

[6] BIS-PI-ARENE-PI-CYCLOPENTADIENYLIRON) DICATIONS [J].

LEE, CC ;

SUTHERLA.RG ;

THOMSON, BJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (15) :907-&

[7] LIGAND-EXCHANGE REACTIONS OF FERROCENE WITH PHENANTHRENE OR 9,10-DIMETHYLPHENANTHRENE IN PRESENCE OF ALUMINUM-CHLORIDE AND ALUMINUM [J].

LEE, CC ;

PANNEKOEK, WJ ;

SUTHERLAND, RG ;

DEMCHUK, KJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 162 (02) :253-269

[8]

NESMEYAN.AN, 1966, DOKL AKAD NAUK SSSR+, V166, P607

[9]

NESMEYANOV AN, 1963, DOKL AKAD NAUK SSSR+, V149, P615

[10] STABILIZATION OF NEGATIVE CHARGE BY COBALTICINIUM NUCLEUS [J].

SHEATS, JE ;

MILLER, W ;

KIRSCH, T .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 91 (01) :97-104