THERMODYNAMIC PROPERTIES OF SOLVENT EXTRACTION OF ANIONS WITH TRIS (1,10-PHENANTHROLINE)IRON(2) CHELATE CATIONS

被引：9

作者：

YAMAMOTO, Y

TARUMOTO, T

IWAMOTO, E

机构：

[1] Department of Chemistry, Faculty of Science, Hiroshima University, Hiroshima

来源：

ANALYTICAL LETTERS | 1969年 / 2卷 / 01期

关键词：

halides; phenthroline-iron(II); solvent extraction; thermodynamic quantities;

D O I：

10.1080/00032716908051265

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Thermodynamic quantities were determined for the extraction of ion pairs of tris(1,10-phenanthroline) iron(II) chelate cations with halide, thiocyanate and perchlorate anions from aqueous phase into nitrobenzene. Ion pairs with larger anions have more negative enthalpy changes with higher extractability. For bromide, the enthalpy change was found to be almost zero and a positive change was observed for chloride. Entropy changes are also discussed. © 1969, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：1 / &

共 6 条

[1] Complex salts of divalent metals containing dipyridyl- and phenathrolin
Pfeiffer, P
Tappermann, F
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1933, 215 (3/4): : 273 - 287
[2] A SPECTROPHOTOMETRIC DETERMINATION OF MERCURY(II) OR CADMIUM(II) BY SOLVENT EXTRACTION WITH 2,2'-DIPYRIDYL IRON(II) CHELATE
YAMAMOTO, Y
KOTSUJI, K
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1964, 37 (04) : 594 - 595
[3] THE SPECTROPHOTOMETRIC DETERMINATION OF ANIONS BY SOLVENT EXTRACTION WITH METAL CHELATE CATIONS .1. A NEW METHOD FOR THE DETERMINATION OF PERCHLORATE IONS
YAMAMOTO, Y
KOTSUJI, K
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1964, 37 (06) : 785 - 788
[4] SPECTROPHOTOMETRIC DETERMINATION OF ANIONS BY SOLVENT EXTRACTION WITH METAL CHELATE CATIONS .20. TRICHLOROACETIC ACID WITH TRIS(1,10-PHENANTHROLINE)IRON(2) CHELATE
YAMAMOTO, Y
KUMAMARU, T
UEMURA, Y
[J]. ANALYTICA CHIMICA ACTA, 1967, 39 (01) : 51 - &
[5] A NEW COLORIMETRIC DETERMINATION OF IODIDE IONS BY SOLVENT EXTRACTION WITH THE 1,10-PHENANTHROLINE-IRON(II) COMPLEX
YAMAMOTO, Y
KINUWAKI, S
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1964, 37 (03) : 434 - 435
[6] YAMAMOTO Y, IN PRESS

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