IONIC-CONDUCTIVITY IN CAF2-XHX

被引:6
作者
VILLENEUVE, G
机构
[1] Laboratoire de Chimie du Solide du C.N.R.S. Université de Bordeaux I 351, cours de la Libération, 33405, Talence Cedex
关键词
D O I
10.1016/0025-5408(79)90219-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
NMR experiments performed on 1H and 19F in CaF1.06H0.94 between 296 and 430 K show a motional narrowing of the proton line for T > 365 K and a rigid lattice behaviour of the fluorine line. Thus, it appears that the ionic conductivity of this material is due to the mobility of H- ions, with an activation energy of 0.45 ± 0.05 eV. © 1979.
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页码:1231 / 1234
页数:4
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