CYCLOPENTADIENYL MOLYBDENUM AND TUNGSTEN DIHALIDES

被引：23

作者：

GREEN, MLH

MOUNTFORD, P

机构：

[1] Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QR, United Kingdom

[2] Imp. Coll. of Science and Technology

[3] Corpus Christi College

[4] Balliol College, Oxford, United Kingdom

[5] Department of Inorganic Chemistry, Oxford University

[6] Harvard University

[7] California Institute of Technology

[8] Hatfield Polytechnic

[9] Wolfson College

[10] Inorganic Chemistry Laboratory, Oxford, United Kingdom

来源：

CHEMICAL SOCIETY REVIEWS | 1992年 / 21卷 / 01期

关键词：

D O I：

10.1039/cs9922100029

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two alternative structures observed for binuclear cyclopentadienyl molybdenum or tungsten dihalides, one with a metal-metal single bond, the other with a triple bond, illustrate 'a delicate balance between metal-metal and metal-ligand bonding'. The 'rich and diverse reaction chemistry' of these complexes is illustrated with reference to the structural type and nature of the halide.

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页码：29 / 38

页数：10

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