OPTICALLY PURE HALOSELENURANES - FIRST SYNTHESIS AND NUCLEOPHILIC SUBSTITUTIONS

被引：47

作者：

TAKAHASHI, T

KUROSE, N

KAWANAMI, S

ARAI, Y

KOIZUMI, T

SHIRO, M

机构：

[1] TOYAMA MED & PHARMACEUT UNIV,FAC PHARMACEUT SCI,TOYAMA 93001,JAPAN

[2] RIGAKU CORP,AKISHIMA,TOKYO 196,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 12期

关键词：

D O I：

10.1021/jo00091a008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first synthesis of optically pure haloselenuranes 1 has been accomplished by utilizing the 2-exehydroxy-10-bornyl group as a chiral ligand. Complete retention of the configuration has been observed in interconversion reactions between haloselenuranes 1 and selenoxide 2 and in nucleophilic substitution reactions of 1.

引用

页码：3262 / 3264

页数：3

共 21 条

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