SOLVENT SELF-DIFFUSION IN GLASSY POLYMER-SOLVENT SYSTEMS

被引：91

作者：

VRENTAS, JS

VRENTAS, CM

机构：

[1] Department of Chemical Engineering, Pennsylvania State University, Pennsylvania 16802, University Park

来源：

MACROMOLECULES | 1994年 / 27卷 / 20期

关键词：

D O I：

10.1021/ma00098a009

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The free-volume theory for solvent self-diffusion in polymer-solvent systems is used to describe the self-diffusion process in glassy polymer-solvent mixtures. General predictions of the theory and comparisons of theoretical predictions with experimental data are considered.

引用

收藏

页码：5570 / 5576

页数：7

相关论文

共 19 条

[1]

BOYER RF, 1970, ENCY POLYM SCI TECHN, V13, P294

[2] PROBE DIFFUSION IN POLYSTYRENE TOLUENE SOLUTIONS [J].

FRICK, TS ;

HUANG, WJ ;

TIRRELL, M ;

LODGE, TP .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1990, 28 (13) :2629-2649

[3] PROBE DIFFUSION IN POLY(VINYL ACETATE) TOLUENE SOLUTIONS [J].

LODGE, TP ;

LEE, JA ;

FRICK, TS .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1990, 28 (13) :2607-2627

[4]

REHAGE G, 1973, PHYSICS GLASSY POLYM

[5] FREE-VOLUME THEORIES FOR SELF-DIFFUSION IN POLYMER SOLVENT SYSTEMS .1. CONCEPTUAL DIFFERENCES IN THEORIES [J].

VRENTAS, JS ;

DUDA, JL ;

LING, HC .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1985, 23 (02) :275-288

[6] ANTIPLASTICIZATION AND VOLUMETRIC BEHAVIOR IN GLASSY-POLYMERS [J].

VRENTAS, JS ;

DUDA, JL ;

LING, HC .

MACROMOLECULES, 1988, 21 (05) :1470-1475

[7] ENERGY EFFECTS FOR SOLVENT SELF-DIFFUSION IN POLYMER SOLVENT SYSTEMS [J].

VRENTAS, JS ;

VRENTAS, CM .

MACROMOLECULES, 1993, 26 (06) :1277-1281

[8] FREE-VOLUME THEORIES FOR SELF-DIFFUSION IN POLYMER SOLVENT SYSTEMS .2. PREDICTIVE CAPABILITIES [J].

VRENTAS, JS ;

DUDA, JL ;

LING, HC ;

HOU, AC .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1985, 23 (02) :289-304

[9] PREDICTIVE CAPABILITIES OF A FREE-VOLUME THEORY FOR SOLVENT SELF-DIFFUSION COEFFICIENTS [J].

VRENTAS, JS ;

CHU, CH ;

DRAKE, MC ;

VONMEERWALL, E .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1989, 27 (05) :1179-1184

[10] FREE-VOLUME INTERPRETATION OF INFLUENCE OF GLASS-TRANSITION ON DIFFUSION IN AMORPHOUS POLYMERS [J].

VRENTAS, JS ;

DUDA, JL .

JOURNAL OF APPLIED POLYMER SCIENCE, 1978, 22 (08) :2325-2339