THE FORMATION OF HOS- FROM DEPROTONATED DIMETHYL-SULFOXIDE AND RELATED SPECIES

被引:10
作者
BOWIE, JH
STRINGER, MB
HAYES, RN
机构
[1] Department of Organic Chemistry, University of Adelaide, South Australia
[2] Department of Chemistry, University of Nebraska, Lincoln, Nebraska
关键词
D O I
10.1002/rcm.1290040409
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Collisional activation of MeSOCH 2− and PhCH2SOC̄HPh (but not PhSOCH 2−) yields an ion of m/z 49, identified as HOS−. It is proposed that this ion is formed following proton transfer to oxygen followed by cyclization and elimination. Copyright © 1990 Heyden & Son Limited
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页码:129 / 130
页数:2
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