STRUCTURAL CHARACTERIZATION OF TITANIUM(III) AMIDE COMPLEXES - A PLANAR GEOMETRY AT NITROGEN IN THE ABSENCE OF TI-N MULTIPLE BONDING

被引：36

作者：

FELDMAN, J

CALABRESE, JC

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 15期

关键词：

D O I：

10.1039/c39910001042

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The titanium(III) complexes [Ti(eta-5-C5Me5)2(NMePh)] and [Ti(eta-5-C5Me5)2(NMePh)(CNBu(n))] have been characterized by X-ray crystallography.

引用

页码：1042 / 1044

页数：3

共 16 条

[1] PLANAR 20-ELECTRON OSMIUM IMIDO COMPLEXES - A LINEAR IMIDO LIGAND DOES NOT NECESSARILY DONATE ITS LONE PAIR OF ELECTRONS TO THE METAL [J].

ANHAUS, JT ;

KEE, TP ;

SCHOFIELD, MH ;

SCHROCK, RR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (04) :1642-1643

[2] INSERTION REACTIONS OF NITRILES IN CATIONIC ALKYLBIS(CYCLOPENTADIENYL)TITANIUM COMPLEXES - THE FACILE SYNTHESIS OF AZAALKENYLIDENE TITANIUM COMPLEXES AND THE CRYSTAL AND MOLECULAR-STRUCTURE OF [(INDENYL)2TI(NCMEPH)(NCPH)]BPH4 [J].

BOCHMANN, M ;

WILSON, LM ;

HURSTHOUSE, MB ;

MOTEVALLI, M .

ORGANOMETALLICS, 1988, 7 (05) :1148-1154

[3] CATIONIC BIS(CYCLOPENTADIENYL)TITANIUM COMPLEXES - THE SYNTHESIS AND STRUCTURE OF [CP-STAR-2TI(OH)(HN=CPH2)]BPH4.ET2O [J].

BOCHMANN, M ;

JAGGAR, AJ ;

HURSTHOUSE, MB ;

MAZID, M .

POLYHEDRON, 1990, 9 (17) :2097-2100

[4] TITANIUM NITROGEN-COMPOUNDS .19. SYNTHESIS AND STRUCTURE OF SPIROCYCLIC TITANIUM SILYLAMIDE [J].

BURGER, H ;

WIEGEL, K ;

THEWALT, U ;

SCHOMBURG, D .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 87 (03) :301-309

[5] N7/O6 CHELATION IN A COMPLEX WITH AN ANALOG OF GUANINE - PREPARATION, SPECTROSCOPIC STUDY, AND CRYSTAL-STRUCTURE OF BIS(ETA-5-CYCLOPENTADIENYL)(THEOPHYLLINATO)TITANIUM(III) [J].

COZAK, D ;

MARDHY, A ;

OLIVIER, MJ ;

BEAUCHAMP, AL .

INORGANIC CHEMISTRY, 1986, 25 (15) :2600-2606

[6] SYNTHESIS OF MONOMERIC PERMETHYLYTTROCENE DERIVATIVES - THE CRYSTAL-STRUCTURES OF ETA-5-C5H5YN(SIME3)2 AND ETA-5-C5H5YCH(SIME3)2 [J].

DENHAAN, KH ;

DEBOER, JL ;

TEUBEN, JH ;

SPEK, AL ;

KOJICPRODIC, B ;

HAYS, GR ;

HUIS, R .

ORGANOMETALLICS, 1986, 5 (08) :1726-1733

[7] CRYSTAL STRUCTURE OF DIETHYLAMINOTITANIUM TRICHLORIDE [J].

FAYOS, J ;

MOOTZ, D .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1971, 380 (02) :196-&

[8] TITANIUM-PROMOTED SYNTHESIS OF A CARBOHYDRAZIDO LIGAND FROM CARBON-MONOXIDE AND DIPHENYLDIAZOMETHANE - DIAZOALKANE COORDINATION AND ACTIVATION BY DICYCLOPENTADIENYLTITANIUM(II) AND VANADIUM(II) COMPLEXES [J].

GAMBAROTTA, S ;

FLORIANI, C ;

CHIESIVILLA, A ;

GUASTINI, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (07) :1918-1924

[9] CYCLOPENTADIENYLDICHLOROTITANIUM(III) - A FREE-RADICAL-LIKE REAGENT FOR REDUCING -N=N- MULTIPLE BONDS IN AZO AND DIAZO-COMPOUNDS [J].

GAMBAROTTA, S ;

FLORIANI, C ;

CHIESIVILLA, A ;

GUASTINI, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (25) :7295-7301

[10]

Lappert M.F., 1980, METAL METALLOID AMID

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