EFFECT OF ION-PAIRS ON THE STEREOCHEMISTRY OF DECARBONYLATION OF ACETYL IODIDE COMPLEXES OF RUTHENIUM - EVIDENCE OF ANION CATALYSIS IN THE CO INSERTION

被引：10

作者：

BELLACHIOMA, G ^{[1
]}

CARDACI, G ^{[1
]}

MACCHIONI, A ^{[1
]}

REICHENBACH, G ^{[1
]}

机构：

[1] UNIV PERUGIA,DIPARTIMENTO CHIM,VIA ELCE SOTTO 8,I-06100 PERUGIA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 427卷 / 03期

关键词：

D O I：

10.1016/0022-328X(92)80083-A

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Decarbonylation of cis,trans-[Ru((COa)-C-13)(COb)(PMe3)2(COMe)I] (2) in the presence of NaBPh4 is stereospecific and gives [Ru(COa)(COb)((COb)-C-13)(PMe3)2Me]+ (3) (a and b indicate CO trans or cis, respectively, to the methyl or the acetyl group); by the principle of microscopic reversibility this demonstrates that the inverse process of insertion is catalyzed by anions.

引用

页码：C37 / C40

页数：4

共 19 条

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