REACTIONS WITH ALKENES OF ETA-2-7-OXOTETRACARBONYLMANGANESE COMPLEXES DERIVED FROM DITERPENOIDS

被引：33

作者：

CAMBIE, RC ^{[1
]}

METZLER, MR ^{[1
]}

RUTLEDGE, PS ^{[1
]}

WOODGATE, PD ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 429卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)83318-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of activated 7-oxotetracarbonylmanganese(I) complexes derived from podocarpic acid (1) and from dehydroabietic acid have been coupled with alkenes to give C(14) functionalised derivatives in high yields. Some coupling reactions resulted in cyclization to C(7), forming 4H-acephenanthrylene derivatives in moderate yields. Several modes of activating these manganese complexes towards coupling reactions were investigated; these included oxidative decarbonylation at room temperature, thermal promotion, and palladium-mediation.

引用

页码：59 / 86

页数：28

共 28 条

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