NEOCLERODANE DITERPENOIDS FROM TEUCRIUM-CORYMBOSUM

被引：13

作者：

BRUNO, M

FAZIO, C

PIOZZI, F

RODRIGUEZ, B

DELATORRE, MC

机构：

[1] UNIV PALERMO, DIPARTIMENTO CHIM ORGAN, I-90123 PALERMO, ITALY

[2] CNR, IST CHIM & TECNOL PROD NAT, I-90123 PALERMO, ITALY

[3] CSIC, INST QUIM ORGAN, E-28006 MADRID, SPAIN

来源：

PHYTOCHEMISTRY | 1995年 / 40卷 / 05期

关键词：

TEUCRIUM CORYMBOSUM; LABIATAE; DITERPENOIDS; 19-NOR-NEO-CLERODANE DERIVATIVE; TEUCORYMBIN;

D O I：

10.1016/0031-9422(95)00519-D

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

A novel 19-nor-neo-clerodane derivative, teucorymbin, and three known neo-clerodanea (19-acetylgnaphalin, teucjaponin A and 6-acetylteucjaponin B) were isolated from the aerial parts of Teucrium corymbosum. The structure of teucorymbin [18-acetoxy-15,16-epoxy-6-oxo-19-nor-neo-cleroda-4,13(16),14-trien-20,12S-olide] was established by chemical and spectroscopic means.

引用

收藏

页码：1481 / 1483

页数：3

相关论文

共 18 条

[1]

BRUNO M, 1995, IN PRESS PHYTOCHEMIS

[2] TRANSFORMATION OF NEOCLERODANE DITERPENOIDS INTO 19-NORNEOCLERODANE DERIVATIVES [J].

DOMINGUEZ, G ;

DELATORRE, MC ;

RODRIGUEZ, B .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (23) :6595-6600

[3] CORRECT STRUCTURES OF MONTANIN-C, TEUPOLIN-I, AND 12-EPI-TEUCVIN, 3 (12R)-NEOCLERODAN-20,12-OLIDES ISOLATED FROM THE TEUCRIUM SPECIES [J].

FAYOS, J ;

FERNANDEZGADEA, F ;

PASCUAL, C ;

PERALES, A ;

PIOZZI, F ;

RICO, M ;

RODRIGUEZ, B ;

SAVONA, G .

JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (10) :1789-1793

[4] TEUCRINS H1-H4, NOVEL CLERODANE-TYPE DITERPENES FROM TEUCRIUM-HYRACANICUM [J].

GACSBAITZ, E ;

RADICS, L ;

OGANESSIAN, GB ;

MNATSAKANIAN, VA .

PHYTOCHEMISTRY, 1978, 17 (11) :1967-1973

[5] C-13 NMR-SPECTRA OF SOME FURANOID DITERPENES FROM TEUCRIUM SPECIES [J].

GACSBAITZ, E ;

KAJTAR, M ;

PAPANOV, GY ;

MALAKOV, PY .

HETEROCYCLES, 1982, 19 (03) :539-550

[6] NEW CLERODANE DERIVATIVES FROM TEUCRIUM-SCORDIUM [J].

JAKUPOVIC, J ;

BARUAH, RN ;

BOHLMANN, F ;

QUACK, W .

PLANTA MEDICA, 1985, 51 (04) :341-342

[7]

MALAKOV PY, 1978, TETRAHEDRON LETT, P2025, DOI 10.1016/S0040-4039(01)94739-2

[8] THE ABSOLUTE STEREOCHEMISTRY OF SOME CLERODANE DITERPENOIDS FROM TEUCRIUM SPECIES [J].

MARTINEZRIPOLL, M ;

FAYOS, J ;

RODRIGUEZ, B ;

GARCIAALVAREZ, MC ;

SAVONA, G ;

PIOZZI, F ;

PATERNOSTRO, M ;

HANSON, JR .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1981, (04) :1186-1190

[9] CLERODANE DITERPENOIDS [J].

MERRITT, AT ;

LEY, SV .

NATURAL PRODUCT REPORTS, 1992, 9 (03) :243-287

[10]

MIYASE T, 1981, CHEM PHARM BULL, V29, P3561