A SIMPLE ROUTE TO (ETA-6-ARENE)TRICARBONYLCHROMIUM COMPLEXES AND A SYSTEMATIC STUDY OF DIFFERENT CATALYSTS FOR COMPLEXATION OF ARENES WITH CR(CO)6

被引：24

作者：

HUDECEK, M

TOMA, S

机构：

[1] Department of Organic Chemistry, Comenius University

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 406卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)83181-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A systematic investigation was made of the catalytic effect of different substances on complexation of toluene with Cr(CO)6. 1-3 molar equivalents of butyl acetate in refluxing decalin was found to be the best catalyst, providing that the complexation was carried out in a special apparatus described earlier. Comparable yields were obtained also in butyl acetate as a solvent, but the reaction time was more than doubled. The utility of the method was verified by complexation of 7 different benzene derivatives.

引用

页码：147 / 151

页数：5

共 10 条

[1] AN IMPROVED METHOD FOR THE SYNTHESIS OF ETA-6-ARENETRICARBONYLCHROMIUM COMPLEXES [J].