STEREOSPECIFIC TETRACYCLIZATION OF ICOSATETRAENES VIA MN(III) PROMOTED OXIDATIVE FREE-RADICAL CYCLIZATION

被引:39
作者
ZORETIC, PA [1 ]
WENG, XY [1 ]
CASPAR, ML [1 ]
DAVIS, DG [1 ]
机构
[1] NIEHS,MOLEC BIOPHYS LAB,RES TRIANGLE PK,NC 27709
关键词
D O I
10.1016/S0040-4039(00)93469-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A stereospecific oxidative free-radical cyclization of polyene 10a to the D-homo-5-alpha-androstane system 11a containing seven asymmetric centers is reported.
引用
收藏
页码:4819 / 4822
页数:4
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