DIRECT BINDING OF ETA-5-PENTAMETHYLCYCLOPENTADIENYL-RHODIUM(III) TO NICOTINAMIDE COFACTORS - A STEP TOWARDS NAD+/NADH RECYCLING

被引：9

作者：

RYABOV, AD

MENGLET, DL

LEVI, MD

机构：

[1] AN FRUMKIN ELECTROCHEM INST, MOSCOW 117071, RUSSIA

[2] MOSCOW MV LOMONOSOV STATE UNIV, DEPT CHEM, MOSCOW 119899, RUSSIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 421卷 / 2-3期

关键词：

D O I：

10.1016/0022-328X(91)86423-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Cp*RhCl2]2 reacts with NAD+ to give [Cp*Rh(NAD+)Cl]+ with rhodium(III) bonded to the adenine ring. The metal-bonded cofactor is accepted by two dehydrogenases. Similar reactions with NADH afford NAD+ and Rh(I) compounds.

引用

页码：C16 / C19

页数：4

共 19 条

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