SYNTHESIS AND STRUCTURE OF THE CLUSTER [NAAU12SE8]3- - AN INORGANIC CRYPTAND COMPLEX

被引：36

作者：

HUANG, SP ^{[1
]}

KANATZIDIS, MG ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 06期

关键词：

D O I：

10.1002/anie.199207871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cube with twelve linearly coordinated gold atoms in the middle of the edges and eight trigonally coordinated selenium atoms at the corners is found in the structure of the title compound 1 (see right). A sodium ion is encapsulated in the center of the cube and interacts with the gold atoms. The (Et4N)3 salt of this inorganic cryptand complex is formed in the reaction of AuCN and Na2Se in the presence of Et4NCl.

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页码：787 / 789

页数：3

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