THE ROLE FO BORON IN NANOCRYSTALLINE FE-ZR-B SOFT-MAGNETIC ALLOYS

被引:48
作者
SUZUKI, K [1 ]
MAKINO, A [1 ]
TSAI, AP [1 ]
INOUE, A [1 ]
MASUMOTO, T [1 ]
机构
[1] TOHOKU UNIV,INST MAT RES,SENDAI,MIYAGI 980,JAPAN
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 1994年 / 179卷 / pt 1期
关键词
D O I
10.1016/0921-5093(94)90255-0
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The microstructure and soft magnetic properties of crystallization-induced alloys in Fe-Zr and Fe-Zr-B systems were investigated. Melt-spun amorphous Fe92Zr, and Fe91Zr7B, alloys were found to crystallize through two distinct stages; the first and second stage are due to primary crystallization of a nanocrystalline b.c.c. phase and crystallization of a residual solute-enriched amorphous phase into Fe3Zr and Fe2Zr respectively. The addition of B into amorphous Fe-Zr alloys causes the refinement of the primary b.c.c. crystals, resulting in a significant improvement of the soft magnetic properties of the annealing-induced alloys. Grain coarsening of the nanocrystalline b.c.c. phase as well as the formation of compounds is suppressed by the addition of B. This is presumably because of a significant increase in the crystallization temperature of the residual amorphous phase resulting from the combined redistribution of Zr and B elements between the primary and parent amorphous phases.
引用
收藏
页码:501 / 505
页数:5
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