PHOSPHONIC SYSTEMS .1. SYNTHESIS AND ADDITION-REACTIONS OF 1-PENTENYLPHOSPHONIC DIAMIDES

被引：2

作者：

MODRO, AM

DEJONGH, CP

MODRO, TA

机构：

[1] Department of Chemistry, University of Pretoria, Pretoria

来源：

TETRAHEDRON | 1990年 / 46卷 / 10期

关键词：

D O I：

10.1016/S0040-4020(01)81537-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of N-substituted 1-pentenylphosphonic diamides was prepared from 1-pentene. These compounds act as acceptors in the conjugate addition of organolithium reagents, yielding 2-substituted pentylphosphonic derivatives. The possibility of a tandem addition - condensation reaction is indicated for these substrates. © 1990.

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页码：3673 / 3682

页数：10

相关论文

共 11 条

[1] A NEW SYNTHESIS OF OLEFINS FROM CARBONYL COMPOUNDS AND PHOSPHONIC ACID BIS AMIDES [J].

COREY, EJ ;

KWIATKOW.GT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (24) :6816-&

[2] SYNTHESIS OF OLEFINS FROM BETA-HYDROXYPHOSPHONAMIDES - STEREOCHEMISTRY AND EXTENSION TO FORMATION OF CONJUGATED DIENES [J].

COREY, EJ ;

CANE, DE .

JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (10) :3053-&

[3]

EDMUNDSON RS, 1988, DICT ORGANOPHOSPHORU, P721

[4] PHOSPHONAMIDE STABILIZED ALLYLIC CARBANIONS - NEW HOMOENOLATE ANION EQUIVALENTS [J].

EVANS, DA ;

TAKACS, JM ;

HURST, KM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (02) :371-378

[5] DESIGN AND REACTIVITY OF TOPOLOGICALLY UNIQUE, CHIRAL PHOSPHONAMIDES - REMARKABLE DIASTEREOFACIAL SELECTIVITY IN ASYMMETRIC OLEFINATION AND ALKYLATION [J].

HANESSIAN, S ;

DELORME, D ;

BEAUDOIN, S ;

LEBLANC, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (19) :5754-5756

[6] NEW SYNTHESIS OF BETA-KETO PHOSPHONATES [J].

HONG, SK ;

CHANG, KH ;

KU, BC ;

OH, DY .

TETRAHEDRON LETTERS, 1989, 30 (25) :3307-3308

[7] MICHAEL ADDITION-REACTIONS OF ETHENYLIDENEBISPHOSPHONATES [J].

HUTCHINSON, DW ;

THORNTON, DM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 346 (03) :341-348

[8] THE PROTOTROPIC EQUILIBRIA IN PENTENYLPHOSPHONIC SYSTEMS [J].

MODRO, AM ;

MODRO, TA .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1988, 66 (07) :1541-1545

[9] CONJUGATE ADDITION OF ALKYL-COPPER AND VINYL-COPPER COMPLEXES TO ALPHA,BETA-UNSATURATED PHOSPHONIC ESTERS - STEREOSPECIFIC SYNTHESES OF GAMMA,DELTA-UNSATURATED PHOSPHONATES [J].

NICOTRA, F ;

PANZA, L ;

RUSSO, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (01) :5-6

[10]

SAVIGNAC P, 1978, SYNTHESIS-STUTTGART, P682