SYNTHESIS AND VIBRATIONAL-SPECTRA OF THE ANTIMONY(V) FLUORIDE-FLUOROSULFATES SBF3(SO3F)2,SBF4(SO3F) AND SB2F9(SO3F)

被引:25
作者
WILSON, WW [1 ]
AUBKE, F [1 ]
机构
[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1W5,BC,CANADA
关键词
D O I
10.1016/S0022-1139(00)81579-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis of the title compounds by a variety of routes is described. These routes involve the oxidation of antimony(III)fluoride by bis(fluorosulfuryl)peroxide and the use of non-statistical ligand redistribution reactions. Complex formation with ClO2SO3F leads to ClO2[SbFn(SO3F)6-n], with n=3 or 4. Polarized Raman data and low temperature infrared data are reported. All antimony(V)fluoride-fluorosulfates are found to have fluorosulfate bridges with SbF3(SO3F)2 and SbF4(SO3F) being polymers. Ionic formulations for the ClO+2 complexes are again based on vibrational spectra. © 1979.
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页码:431 / 445
页数:15
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