SUPERCOOLED LIQUIDS - A NEW LOOK AT SELECTED RELAXATION PHENOMENA

被引:3
作者
KIVELSON, D
GREENFIELD, M
GOMPERTS, S
机构
[1] Department of Chemistry and Biochemistry, University of California, Los Angeles
基金
美国国家科学基金会;
关键词
D O I
10.1016/0022-3093(91)90324-Y
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Along with the presentation of the results of some new light-scattering measurements, other observations concerning supercooled liquids are interpreted. The following are examined: (1) the bifurcation of rotational relaxation in supercooled liquids into alpha- and beta-processes, (2) the residual light-scattering linewidths (near and below T(g)) of the Brillouin and shear-wave lines, (3) the fact that the viscoelastic invariant, 2(-1)-mu-J(r)(0)(tau-m/tau-r)-beta, is close to unity for many supercooled liquids (where J(r)(omega) is the retardational compliance, mu the shear modulus, tau-m the Maxwell relaxation time, and tau-r the relaxation time and beta the exponent used in a fit of J(r)(omega) to a Cole-Davidson function).
引用
收藏
页码:327 / 334
页数:8
相关论文
共 38 条
[1]   ON TEMPERATURE DEPENDENCE OF COOPERATIVE RELAXATION PROPERTIES IN GLASS-FORMING LIQUIDS [J].
ADAM, G ;
GIBBS, JH .
JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (01) :139-&
[2]   MOLECULAR-DYNAMICS OF VISCOUS-LIQUIDS - COMPARISON OF DIELECTRIC AND KERR-EFFECT RELAXATION FOR TRITOLYL PHOSPHATE, ORTHO-TERPHENYL AND THEIR MIXTURES [J].
BEEVERS, MS ;
CROSSLEY, J ;
GARRINGTON, DC ;
WILLIAMS, G .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1977, 73 :458-470
[3]   DISTRIBUTION OF RELAXATION-TIMES IN (KBR)0.5(KCN)0.5 [J].
BIRGE, NO ;
JEONG, YH ;
NAGEL, SR ;
BHATTACHARYA, S ;
SUSMAN, S .
PHYSICAL REVIEW B, 1984, 30 (04) :2306-2308
[4]   THEORY OF DEPOLARIZED LIGHT-SCATTERING [J].
CHAPPELL, PJ ;
ALLEN, MP ;
HALLEM, RI ;
KIVELSON, D .
JOURNAL OF CHEMICAL PHYSICS, 1981, 74 (11) :5929-5941
[5]   A COMPREHENSIVE LIGHT-SCATTERING STUDY OF A LIQUID COMPOSED OF SYMMETRIC TOP MOLECULES [J].
CHAPPELL, PJ ;
KIVELSON, D .
JOURNAL OF CHEMICAL PHYSICS, 1982, 76 (04) :1742-1753
[6]  
Debye P., 1929, POLAR MOL
[7]   H-2-NMR STUDY OF THE GLASS-TRANSITION IN SUPERCOOLED ORTHO-TERPHENYL [J].
DRIES, T ;
FUJARA, F ;
KIEBEL, M ;
ROSSLER, E ;
SILLESCU, H .
JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (04) :2139-2147
[8]  
GREENFIELD M, COMMUNICATION
[9]  
Harrison G., 1976, DYNAMIC PROPERTIES S
[10]   NANOSECOND AND MICROSECOND STUDY OF PROBE REORIENTATION IN ORTHOTERPHENYL [J].
HYDE, PD ;
EVERT, TE ;
EDIGER, MD .
JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (04) :2274-2279