SYNTHESIS OF A STABLE ARENESULFENIC ACID BEARING A BOWL-SHAPED MACROBICYCLIC CYCLOPHANE SKELETON

被引：70

作者：

GOTO, K ^{[1
]}

TOKITOH, N ^{[1
]}

OKAZAKI, R ^{[1
]}

机构：

[1] UNIV TOKYO,GRAD SCH SCI,DEPT CHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 10期

关键词：

CYCLOPHANES; KINETIC STABILIZATION; SULFENIC ACIDS;

D O I：

10.1002/anie.199511241

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A wealth of highly selective reactions may become accessible thanks to the approach described herein: A reactive functional group is placed on the inside of a bowl‐shaped molecular skeleton; in this way, for example, dimerizations can be prevented, but reactions with added small molecules remain possible. The sulfenic acid 1 obtained from the corresponding S‐butyl sulfoxide by pyrolysis is stable both in the solid state and in solution, and reacts smoothly with methyl propiolate and butanethiol. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1124 / 1126

页数：3

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