ASYMMETRIC MIXED-VALENCE MANGANESE COMPLEXES CONTAINING THE [MNIII(MU-O)2-(MU-MECO2)MNIV]2+ CORE AND THEIR CATALASE REACTIVITY

被引：87

作者：

BOSSEK, U ^{[1
]}

SAHER, M ^{[1
]}

WEYHERMULLER, T ^{[1
]}

WIEGHARDT, K ^{[1
]}

机构：

[1] RUHR UNIV BOCHUM,LEHRSTUHL ANORGAN CHEM 1,W-4630 BOCHUM,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 24期

关键词：

D O I：

10.1039/c39920001780

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two asymmetrically ligated, dinuclear, mixed valence complexes [MnIVL(mu-O)2(mu-MeCO2)MnIII(MeCO2)2] 1 and [MnIVL(mu-O)2(mu-MeCO2)MnIII(bpy)(MeOH)](ClO4)2.MeOH 2b have been synthesized (L = 1,4,7-trimethyl-1,4,7-triazacylononane, bpy = 2,2'-bipyridyl) and their structures have been determined by X-ray crystallography; 1 and 2b catalyse the disproportionation of aqueous H2O2.

引用

页码：1780 / 1782

页数：3

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