CRYSTAL TO MOLECULAR CHIRALITY TRANSFER - SUPRAMOLECULAR PHOTOCHEMISTRY OF CRYSTALLINE CARBOXYLATE SALTS

被引：28

作者：

JONES, R ^{[1
]}

SCHEFFER, JR ^{[1
]}

TROTTER, J ^{[1
]}

YANG, J ^{[1
]}

机构：

[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 1Z1,BC,CANADA

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 38期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0040-4039(00)61122-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Solid state irradiation of a salt formed between a prochiral, photochemically reactive carboxylic acid and a non-absorbing, optically active amine is shown to lead to an optically active Norrish type II photoproduct whose optical purity depends on the dimorphic crystalline modification photolyzed.

引用

页码：5481 / 5484

页数：4

共 15 条

[1] ABSOLUTE ASYMMETRIC INDUCTION DIFFERENCES IN DUAL PATHWAY PHOTOREACTIONS
CHEN, JX
POKKULURI, PR
SCHEFFER, JR
TROTTER, J
[J]. TETRAHEDRON LETTERS, 1990, 31 (47) : 6803 - 6806
[2] STEREOSELECTIVITY REVERSAL OF A PHOTOCHEMICAL-REACTION IN THE SOLID-STATE
EVANS, S
OMKARAM, N
SCHEFFER, JR
TROTTER, J
[J]. TETRAHEDRON LETTERS, 1985, 26 (48) : 5903 - 5906
[3] USE OF CHIRAL SINGLE-CRYSTALS TO CONVERT ACHIRAL REACTANTS TO CHIRAL PRODUCTS IN HIGH OPTICAL YIELD - APPLICATION TO THE DI-PI-METHANE AND NORRISH TYPE-II PHOTOREARRANGEMENTS
EVANS, SV
GARCIAGARIBAY, M
OMKARAM, N
SCHEFFER, JR
TROTTER, J
WIREKO, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (18) : 5648 - 5650
[4] REACTIVITY DIFFERENCES BETWEEN DIMORPHS IN A CRYSTALLINE PHASE NORRISH TYPE-II REACTION
EVANS, SV
OMKARAM, N
SCHEFFER, JR
TROTTER, J
[J]. TETRAHEDRON LETTERS, 1986, 27 (13) : 1419 - 1422
[5] MECHANISTIC PHOTOCHEMISTRY OF 1-ADAMANTYLACETONE
GAGOSIAN, RB
DALTON, JC
TURRO, NJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (18) : 5189 - 5192
[6] ASYMMETRIC INDUCTION IN THE SOLID-STATE PHOTOCHEMISTRY OF SALTS OF CARBOXYLIC-ACIDS WITH OPTICALLY-ACTIVE AMINES
GUDMUNDSDOTTIR, AD
SCHEFFER, JR
[J]. TETRAHEDRON LETTERS, 1990, 31 (47) : 6807 - 6810
[7] ASYMMETRIC INDUCTION IN THE SOLID-STATE PHOTOCHEMISTRY OF AMMONIUM-SALTS
GUDMUNDSDOTTIR, AD
SCHEFFER, JR
[J]. PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1991, 54 (04) : 535 - 538
[8] ENTROPIC CONTROL OF PHOTOCHEMICAL REACTIVITY - TRANSITION-STATE FOR GAMMA-HYDROGEN ABSTRACTION OF ALKYL PHENYL KETONES
LEWIS, FD
JOHNSON, RW
KORY, DR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (19) : 6100 - 6107
[9] RAMAMURTHY V, 1991, PHOTOCHEMISTRY ORG C, pCH7
[10] SOME ASPECTS OF PHOTOCHEMICAL AND MASS SPECTRAL BEHAVIOR OF BRIDGEHEAD ACETONE DERIVATIVES
SAUERS, RR
GORODETS.M
WHITTLE, JA
HU, CK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (21) : 5520 - &

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