A NOVEL PHOTOINDUCED FENTON REACTION - PERFLUORINATED POLY(P-PHENYLENE)-CATALYZED PHOTOHYDROXYLATION OF BENZENE WITH O2 AND H2O TO PHENOL

被引：10

作者：

MARUO, K ^{[1
]}

WADA, Y ^{[1
]}

YANAGIDA, S ^{[1
]}

机构：

[1] OSAKA UNIV, FAC ENGN, SUITA, OSAKA 565, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 03期

关键词：

D O I：

10.1246/cl.1993.565

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

O-18 Tracer study of perfluorinated poly(p-phenylene)-catalyzed photohydroxylation of benzene to phenol with (H2O)-O-18 and O-16(2) revealed that the hydroxylation initially occurs by the attack of the hydroxyl radical (HO.)-O-18 generated by the photooxidation of (H2O)-O-18, but the hydroxyl radical (HO.)-O-16 derived from the concurrently produced (H2O2)-O-16 comes to participate in further hydroxylation as the photocatalysis proceeds.

引用

页码：565 / 566

页数：2

共 5 条

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[5] MARUO K, IN PRESS B CHEM SOC

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