FREE-RADICALS FROM BIOGENIC VOLATILE ORGANIC-COMPOUNDS (VOCS) - AN ELECTRON-SPIN-RESONANCE INVESTIGATION

被引：6

作者：

HUDSON, A ^{[1
]}

WATERMAN, D ^{[1
]}

ALBERTI, A ^{[1
]}

机构：

[1] CNR,ICOCEA,I-40129 BOLOGNA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1995年 / 12期

关键词：

D O I：

10.1039/p29950002091

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electron spin resonance has been used to characterise free radicals formed by the reactions of photochemically generated tert-butoxyl radicals with alpha-pinene, beta-pinene, alpha-terpinene, gamma-terpinene, car-2-ene, car-3-ene and limonene. The spectra have been interpreted using computer analysis and simulation and assigned to substituted cyclohexenyl or cyclohexadienyl radicals formed by abstraction of a hydrogen atom from the parent terpene.

引用

页码：2091 / 2093

页数：3

共 14 条

[1] RATE CONSTANTS FOR THE GAS-PHASE REACTIONS OF O-3 WITH A SERIES OF MONOTERPENES AND RELATED-COMPOUNDS AT 296-K +/-2-K [J].