INTERPRETATION OF SOLVENT EFFECTS ON STYRENE-MALEIC ANHYDRIDE COPOLYMER SEQUENCE DISTRIBUTION AND MICROSTRUCTURE IN TERMS OF THE BOOTSTRAP EFFECT

被引：23

作者：

KLUMPERMAN, B ^{[1
]}

BROWN, PG ^{[1
]}

机构：

[1] UNIV NEW ENGLAND,DEPT CHEM,ARMIDALE,NSW 2351,AUSTRALIA

来源：

MACROMOLECULES | 1994年 / 27卷 / 21期

关键词：

D O I：

10.1021/ma00099a023

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Solvent effects on the copolymerization of styrene and maleic anhydride are interpreted in terms of Harwood's bootstrap effect. Earlier observations that this comonomer pair behaves according to the bootstrap effect are confirmed. Furthermore, solvent effects on stereochemical configuration can be interpreted in terms of the bootstrap effect as well. The observation that the Z/E ratio of the anhydride units versus copolymer composition is independent of solvent is attributed to monomer partitioning between the bulk of the solution and the locus of polymerization.

引用

页码：6100 / 6101

页数：2

共 8 条

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